If ‘→’ denotes increasing order of intensity, then the meaning of the words [walk → jog → sprint] is analogous to [bothered → ________ → daunted]. Which one of the given options is appropriate to fill the blank?

Two wizards try to create a spell using all the four elements, water, air, fire, and earth. For this, they decide to mix all these elements in all possible orders. They also decide to work independently. After trying all possible combination of elements, they conclude that the spell does not work.
How many attempts does each wizard make before coming to this conclusion, independently?